The Supreme Satanic System - Chapter 221 Night Assassin Troops!!!

I want an S-Rank skill too! I want it so badly, I could die for it![You have awakened an S-Rank skill.] [But it only works when you die.]Eh !? WHAT IS THE POINT OF GETTING ONE IF I DIE !?

For Cain, the promised land of opportunity in the Pokémon World was not the paradise he imagined. Instead, he fell into the hands of the sinister Team Rocket, a prisoner on an island where darkness devours hope.However, even in the most desperate moments, fate did not abandon him entirely. A strange twist brings him back to the beginning of it all, to the place where his dreams were buried under the shadows.Now, with the knowledge and scars of his previous life, Cain has the chance to correct the course of his destiny.Free from the chains of the past, he must forge his own path in a world full of mysteries and dangers. With new allies and old enemies, the battle for his freedom will not be easy, but Cain has decided that this time he will not fail. Neither against the Pokémon nor the humans who stand in his way.

Young Chen Xiang had a fateful encounter with a goddess & demoness and received their peerless heritage, divine pulses, ultimate martial arts, and transcendent alchemy techniques, which gave him an easy ride in his journey of cultivation.

When hungry, he refines some spirit pills to eat as snack, when lonely he flirts with the goddesses, when bored he teases those martial artists who came to beg for spirit pills, when tired he lets his beautiful wives massage him.

- Description from Novelupdates

After the nuclear warfare, massacres started to spread throughout the entire world. The order between humans completely collapses, and the strong eats while the weak gets eaten becomes the #1 rule.